This year's theme was the Models as Muse: Embodying Fashion, and was hosted by Marc Jacobs, Justin Timberlake, Kate Moss, and Anna Wintour.
The guests wore their best suits and gowns, and some of them made more daring fashion choices: Kate Moss sported a gold lame turban, Rihanna wore a Dolce & Gabbana suit, and Madonna turned heads in her Louis Vuitton ensemble, bunny ears and everything.
The Gossip Girls, Blake Lively and Leighton Meester didn't do to well on their fashion choices, with Lively's teal Versace dress with its high-cut slit up the side, and Meester's floral Vuitton emsemble. Blair and Serena would be disgusted.
Agyness Deyn resembled Marilyn Monroe with a short blonde bob and a silver Burberry gown, and Heidi Klum's very pregnant physique was extremely noticeable in her J. Mendel dress, even though it was meant to hide the bump.
Here are some of the most memorable looks of the night!
Kate Moss with Marc Jacobs in his design.
Mary-Kate Olsen in Christian Lacroix Haute Couture.
Vogue editor-in-chief, Anna Wintour in Chanel Haute Couture.
Jessica Biel in Versace Atelier, with Justin Timberlake in William Rast.
Ashley Olsen in The Row.
Kate Bosworth in Stella McCartney.
Anne Hathaway in Marc Jacobs.
Rihanna in Dolce & Gabbana.
Chanel Iman in Zac Posen.
Emma Roberts in Versace.
Miranda Kerr in Jil Sander.
Blake Lively in Versace.
Iman in Donna Karan.
Tyra Banks in Badgley Mischka.
Agyness Deyn and Twiggy, both in Burberry.
Heidi Klum in J. Mendel.
Victoria Beckham in Marc Jacobs.
Gisele Bundchen in Versace.
Kate Beckinsale in Marchesa.
Leighton Meester in Louis Vuitton.
Elizabeth Hurley in Elie Saab.
Jessica Stam in Rodarte.
Madonna in Louis Vuitton.
Marion Cotillard in Christian Dior, with John Galliano.
Isaac Mizrahi with Coco Rocha in his design.Images via nymag.com, style.com, zimbio.com
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